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weinan

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August 20, 2021

Hi all,

I'm weinan, this is my first post.

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A tautomeric ligand enables directed C‒H hydroxylation with molecular oxygen

October 14, 2021

This paper report a new synthetic pathway to do directly aromatic hydroxylation using a tautomeric ligand, the substrate scope is broad. https://www.science.org/doi/10.1126/science.abg2362

Ruthenium-Catalyzed Enantioselective C–H Functionalization: A Practical Access to Optically Active Indoline Derivatives

October 25, 2021

This paper provide a new synthetic strategy to syntheis indoline derivatives by using commercial available chiral transient amine, gives a good ee( up to 94%) and also shows some potential application to some drug molecules. It provide a practical way to control the intramolecular enantioselective C-H activation. https://pubs.acs.org/doi/10.1021/jacs.9b07251

A new chiral amine has been synthesized

October 25, 2021

This new chiral amine has a methoxyl group in the ortho positions, which may contribute some hydrogen bonding to arene ligands.

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