Phosphines: preparation, reactivity and applications

As we all know phosphines are important ligands in organic metalic, one can synthesis different Phosphines ligand to contro the reactivity, e.g, with electron donating group, a Phosphines ligands can enrich the electrodensity in metal center and improve the rate of oxidative addition. in addition, by modify the phosphines ligands, one can control the steric of reaction center, the advantage is not only control the selectivity but also improve the reaction rate for dissociation mechanism. This paper has very comprehensive rewiew on phosphine ligand, including ligands synthesis and application. https://pubs.rsc.org/en/content/chapterhtml/2019/bk9781788014991-00001?isbn=978-1-78801-499-1